Brochure_TitroLine-7800_0.9-MB_PDF-English

TitroLine® 7800 The first address for Titration TitroLine® 7800 - The universal titrator with IDS® technology The TitroLine® 7800 enhanced the universal features of the TitroLine® 7750 with an additional IDS® measurement input. Hence the TitroLine® 7800 is able to perform potentiometric titrations with analogue or IDS® electrodes up to volumetric Karl Fischer titrations. The IDS® measuring input is multifunctional. Digital sensors for the determination of pH and ORP value, the conductivity up to the dissolved oxygen can be connected. IDS® stands for „intelligent, digital sensors“ and means that the analog measuring signal is converted into a digital measuring value in the sensor. This protects the signal from external interferences, such as moisture, electro-magnetic fields or pulses. The higher measuring accuracy raises confidence in your readings to a whole new level. TitroLine® 7800 with accessories Benefits TitroLine® 7800 Highly visible full color display, that can be easily viewed from a distance and extreme angles With new interchangeable modules which all relevant reagent and unit data can be stored Thanks to the 2 x USB-host, 1 x USB-PC and 2 x RS232 ports very expandable. Connectable are e.g. USB keyboard, USB printer, barcode reader, USB flash drives, balances, PC und further SI Analytics devices such as piston burettes and sample changers Storage of results using via USB port (PDF – and CSV -format) including method transfer With standard methods for potentiometric and KF titration Second digital measuring port for intelligent digital sensors (IDS®) Selection table titration – TITRONIC® and TitroLine® The most important features of titrators TitroLine® and piston burettes TITRONIC® at-a-glance ApplicationTITRONIC® 500 TitroLine® 6000 TitroLine® 7000 TitroLine® 7500 KF TitroLine® 7500 KF trace TitroLine® 7750 TitroLine® 7800 Intelligent interchangable units (5, 10, 20 and 50 ml) — Manual titration — — Dosing — Solutions preparation (manually or automatically with connected balance) — Automatic titration (independent with external software) 1) pH/mV titrations „aqueous“ (Alkalinity, hydrochloric acid, citric acid, Kjeldahl…) — — — pH/mV titrations „non aqueous““ (TAN/TBN, FFA, titrations with perchloric acid…) — — — — Redox titrations (iodometry, permanganometry….) — —— Redox titrations (COD) — —— Halide titrations (chloride, “salt“…) — —— Hydrogen sulphide and mercaptans —— — — Sulfurous acid in wine and beverages — —— Bromine number — Cond measurement with ID sensors (IDS®)——— — — — pH-stat-applications (enzyme kinetics, soil samples, biotechnology) — — — — Water analysis according to KF Volumetric method (10 ppm – 100 %) — —— — Water analysis according to KF Coulometric method (1 ppm – 5 %) — —— — — — Applications with sample changer —— — — Applications with TitriSoft — 1) Can be used as titration and dosing burette in automatic titration systems 3 2 Titration curve total hard- ness (calcium and magne- sium) Typical application example for two equivalence points: Titration of amino hydrochlorides (method according Ph. EUR). Up to now the amino hydrochlorides were dissolved in glacial acetic acid, the amines released through the addition of mercuric acetate and titrated with perchloric acid in glacial acetic acid. According to the environmentally friendly method of the European Pharma- copeia the amino hydrochlorides are dissolved in ethanol and being dosed with exact 5.00 ml of a 0.01 mol/l HCl. This mixture is then titrated with NaOH 0.1 mol/l. Most titration curves show two equivalence points. The result is calculated from the difference between the first and second equivalence point. This method, with all parameters and calculation formulas, comes standard in the TitroLine® 7800 and can be used after the input of equivalent substance weight. Besides the specifica- tions of the series and the TitroLine® 7750, the TitroLine® 7800 pro- vides more functions. Ideal for measure- ments/titration tasks with pH and Cond. Typical example: Measurement of the pH value and Cond, then titra- tion of the acid capacity. Measurement and calibration with the highest accuracy The wireless sensor recognition automatically recognizes SI Analytics ID and IDS electrodes which instantly send the specific data to the titrator. Therefore TitroLine® 7800 always uses correct calibration data. False measurements became impossible. Perfect for non-aqueous titrations Eliminate the need for special electrodes (e.g. separate indicator, ref- erence and auxiliary electrodes) with the built-in amplifier–ideal for titrations in non-aqueous solvents such as: • Acid and base numbers in oils. • Titrations in glacial acetic acid with perchloric acid. • Hydroxyl, NCO (Isocyanate) number and further specific values. pH Stat Titrations With a pH stat application, a given pH is first adjusted and then kept constant during the analysis with an acid or a base. The pH stat titration is often applied to: • Determination of the enzyme activity (ex. Lipase). • pH stat elution of soil sample at pH 4. • Monitoring of the pH value during chemical synthe- ses. More equivalence points to expand application possibilities Yes, it is now possible to detect and calculate up to two equivalence points during one titration. It is possible to determine both the calcium and mag- nesium hardness individually in a sin- gle step. TitroLine® 7800 – Featuring enhanced automation and additional methods Connections 5 4 2 I – I2 I2 Volumetry Iodine dosing KF reaction Karl Fischer Titration – the method for determining water Experienced analyst may be unpleasantly reminded by the pyridine smell, when hearing the name Karl  Fischer. However, modern reagents and most user- friendly analyzing instruments have eliminated the problem. Nowadays all applications can be handled and processed very easily by using the coulometric and volumetric Karl Fischer titra- tion instruments. Thanks to its selectivity and precision, the Karl Fischer titration very easily and accurately established as the most important method for determining water and humidity. The basic principle of the water determination according to Karl Fischer (short: KF) is a reaction of iodine with water in an alcoholic solution with presence of sulfu- rous acid and a base. With the volumetric method the iodine can be accurately added through a piston burette (fig.). The way of dosing: Titration curve live The online display of the measurement curve, measurement drift and titration solvent consumption (TitroLine® 7500 KF only) make accurate monitoring of the titration possible and one can determine any unwanted side reactions immediately. Karl Fischer titration made easy 7 6 TitroLine® 7800 - Technical data DisplayColor graphics 3.5 inches -1/4 VGA TFT display with 320x240 pixels Measurement input 1 (analogue) pH/mV with reference electrode input pH/mV-input with 24 bit transducer Electrode socket according to DIN 19 262 or additional with BNC socket insert RFID receiver for SI Analytics® ID electrodes - 3.0 ... 18.00 / - 2000 ... 2000 0.001 / 0,1 0.002 / 0.1 mV ± 1 Digit Measurement range pH/mV Display resolution pH/mV Accuracy pH/mV (without sensor) - 3.0 ... 18.00 / - 2000 ... 2000 0.001 0.1 0.002 0.1 mV ? 1 Digit Measurement input 2 (IDS) Accuracy +/- 1 digit in dependence from the used IDS-electrode pH 0.000 … 14.000 +/-0.004 pH mV +/- 1200.0 mV +/- 0.2 mV Temperature -5.0 … 105.0. °C +/- 0.2 °C Conductivity 0.00 … 2000 mS/cm +/- 0.5 % from m.v. Calibration pH (analogue and IDS) 2 or 3 – point calibration with DIN/NIST or technical buffers. Own buffers can be programmed. Calibration conductivity (IDS) 1 point with 0.01 mol/l KCl Temperature compensation conductivity (IDS) Automatic/manual nLF non-linear function natural waters according EN 27888 and ultra-pure water function, linear compensation from 0.000… 10.000 %/K Measurement input Dead stop (2 x 4 mm socket) Measurement range µA Display resolution µA Accuracy µA (without sensor) Connector (µA) for double platinum electrodes Polarization voltage variably adjustable 40 … 220 mV 0 ... 100 0.1 0.2 ± 1 digit Measurement input temperature (2 x 4 mm socket) Measurement range temperature °C Display resolution ° Accuracy °C (without sensor) For Pt 1000 resistance thermometer NTC 30 kOhm - 75 ... 175 -40 … 170 °C 0.1 0.2 K ± 1 digit/0.3 K ± 1 digit Interfaces 1 x LAN, 2 x USB-A, 1 x USB-B 2 x RS 232 Balance connection RS 232 Printer (USB-A) HP PCL, Seiko DPU S445, PDF Housing material Polypropylene Front keyboard Polyester coated Housing dimensions 15.3 x 45 x 29.6 cm (W x H x D), height with interchangeable unit Ambient conditions Ambient temperature + 10 ... + 40 °C for operation and storage Weight 2.3 kg for basic unit, 3.5 kg for complete device incl. interchangeable unit (with empty reagent bottle, without magnetic stirrer) Ambient conditions Ambient temperature: + 10 ... + 40 °C for operation and storage Intelligent interchangeable modules (5, 10, 20 and 50 ml) Valve: PTFE/ETFE Cylinder: borosilicate glass 3.3 (DURAN®) Hoses FEP, blue Burette resolution (steps) 10,000 Dosing accuracy according DIN EN ISO 8655, part 3 Accuracy : >0.15 % Precision: >0.05 - 0.07 % (Depending on the used interchangeable unit) Measurement range/ resolution/ Accuracy (all values ±1 digit), according to the used ID sensor (IDS®) pH 0.000 … 14.000 +/-0.004 pH mV +/- 1200.0 mV +/- 0.2 mV temperature -5.0 … 105.0 °C +/- 0.2 °C conductivity 0.00 … 2,000 mS/cm +/- 0.5 % v. Mw. Calibration pH calibration points 1-, 2-, 3-point stored buffers SI Analytics® technical and DIN buffer Calibration cell constant cond, according to the used ID sensor (IDS®) solid 0.475cm-1; 0.100cm-1; 0.010cm-1 calibratable (1 point) 0.450 to 0.500cm-1, 0.800 … 0.880 cm-1, standard: 0.01 mol/L KCl adjustable 0.250 … 25.000cm-1; 0.090 … 0.110 cm-1 Temperature compensation cond, according to the used ID sensor (IDS®) set-up automatically/manually temperature coefficient nCond: non-linear function natual waters after EN 27 888 and high-purity water function Linear compensation 0.000 … 10.000 %/K no compensation Manual titration Measurement pH. mV and cond. single and continous Measurement parallel (e.g.. pH + cond.) single and continuously Solution preparation (manual or automatic when connected to balance) Titration to mV and pH end points 2 EP Dynamic and linear titration to inflection points (EQ) mV and pH 2 EQ Particularly suitable for non-aqueous titrations Dead-stop-titration pH-stat-titration Water determination according to KF volumetry (10 ppm – 100 %, recommended) Standard methods Number of user methods 50 Connection and control of autosamplers Can be controlled with TitriSoft 3.2 9 8 IDS® Sensors The measuring signals are trans- mitted without interference Perfect galvanized separation Resistant against environmental influences Effortless allocation and docu- mentation of the sensor to elec- tronically captured and saved calibration results Highest possible operator comfort and measuring accuracy IDS® Electrodes - The intelligent sensors When determining the pH value, there are very high requirements of the sensor and the transmission of the measuring value from the sensor to the measuring device. The sensitive measuring signals and very high interior resistors of the sensors require a very complex shielded signal transfer to the measuring device in analog systems. If there is moisture present on the contacts, this can change the measuring value all the way to a complete failure of the measurement. This risk is eliminated by the IDS tech- nology. The measuring value is processed in the sensor, then digitalized and transmit- ted to the device without interference. When the IDS® sensors are connected to the measur - ing device, they automatically identify themselves with their serial numbers and type designation and transmit their calibration data to the device. With conventional systems, the sensor must be calibrated with every sensor change, as the calibration data is merely saved in the devices and is only available with the combination device- sensor. The IDS® concept helps here as well due to its calibra- tion, which is saved in the sensor. Every sensor brings along its own calibration. There is no mandatory calibration when the sen- sor is changed in order to obtain a safe measurement. The already proven analog SI Analytics sensors are used as sensors. The possibility to distinguish between sensors of the same type by their serial numbers allows the easy allocation and documentation of elec- tronically recorded and saved measurement results. Advantages IDS® Electrodes 11 10 Type no.Order NoDescription TitroLine® 7800 285220980TitroLine® 7800 basic unit with two measuring inputs, one analogue and one digital (IDS) measuring input TitroLine® 7800 285220990TitroLine® 7800 basic unit with two measuring inputs, one analogue and one digital (IDS) measuring input, with mag- netic stirrer TM 235 Electrodes, exchangeable units and further accessories have to be ordered separately Required accessories for the volumetric KF titration Type no. Order NoDescription TM 235 KF, 115-230 V 285220900Titration stand with pump. Scope of delivery: Basic unit with 1 l DURAN® reagent bottle TZ 1791, 1 l DURAN® waste bottle TZ 1792, moisture bottle, tubes and screw threads, power supply TZ 1855 (110 ... 240 V) TZ 1770 285216677Karl Fischer titration vessel. DURAN® glass vessel TZ 1775 (approx. 30...150 ml), removable head made of polypropyle- ne/PTFE, 1 drilling NS 19, NS 14,5, NS 7,5 and 3 drillings with screw threads, titration tip, moisture trap and weighing funnel KF 1100 285102030Micro double platinum electrode for Karl Fischer titrations, with fixed cable, double platinum pin and tapper NS 7.5 for TZ 1770 and TZ 1772 TZ 1748 285216560Stand rod stainless steel Ø 10 mm TZ 1789 285221120Starter kit KF consisting of molecular sieve, needles with syrin- ges and glass wool Recommended exchangeable units for the KF titration Type no. Order NoDescription WA 05 2852203005 ml exchangeable unit with integrated chip for reagent data, with brown glass bottle for titrant, GL 45 and S 40-bottle ad- apter, tubes, drip tube and titration tip WA 10 28522031010 ml exchangeable unit with integrated chip for reagent data, with brown glass bottle for titrant, GL 45 and S 40-bottle adapter, tubes, drip tube and titration tip WA 20 28522032020 ml exchangeable unit with integrated chip for reagent data, with brown glass bottle for titrant, GL 45 and S 40-bottle adapter, tubes, drip tube and titration tip Order information Titrators Order information Type-Nr. Order No.Description A 157 IDS IDS ® 4 pole conductivity cell, plastic shaft, 3 m cable with digital plug, sensor material graphite, cell constant 0.475 cm-1, temp.-sensor NTC 30 kOhm, length 120 mm, 15.3 mm Ø, -5...+80 °C A 162 IDS 285100120Glass shaft, Pt junction, electrolyte KCl 3 mol/l, Silamid® refe- rence, temp. sensor NTC 30 kOhm, sphere membrane, A glass, ?'3? C?
%7?n FH?e 7(X?? 7?y?? ?fc` 8A2 &?W8 x?xt@ #c??? #Apyb &?Qt? -5...+100 °C, 0...14 pH A 7780 IDS 285101080x4?c #6d? H??` #)??? )sG8N "e4 E$?m @?@ %&? reference system, temperature sensor NTC 30 kOhm, sphere 1t?(p@rW?? ?'3? C?
%7?n FH?e 7(X?? 7?y?? ?fc` 8A2 120 mm, 12 mm Ø, -5...+80 °C, 0...14 pH BlueLine 14 pH IDS 285129140Glass shaft, platinum junction, electr. KCl 3 mol/l, Ag/AgCl- reference system, temp.-sensor NTC 30 kOhm, cone mem- Ar??0@rW?? ?'3? C?
%7?n FH?e 7(X?? 7?y?? ?fc` AT?% A? &?W8 mm, 12 mm Ø, -5...+100° C, 0...14 pH BlueLine 31 RX IDS 285129310Glass shaft, ceramic junction, electrolyte KCl 3 mol/l, Ag/AgCl- reference system, temp.-sensor NTC 30 kOhm, sensor plati- b0EqFTQ?#Apyb&?Qt??'3?C?
%7?Q FH?H7(X??7?y???fc`AT?% A?&?W8 mm, 12 mm Ø, -5...+100 °C FDO1100IDS 28520244055p???GtD05!VW ??bXe(#6d? 6?95!V)y?'3?C?
%7?Q FH?H7(X??7?y?? plug, length 150 mm, 15.3 mm Ø, 0...+50 °C LF413T IDS 285202410IDS® 4 pole cell, plastic shaft, 1.5 m cable with digital plug, sensor material graphite, cell constant 0.475 cm-1, temp.-sen- sor NTC 30 kOhm, length 120 mm, 15.3 mm Ø, -5...+80 °C LF413T3MIDS 285202420IDS ® 4 pole conductivity cell, plastic shaft, 3 m cable with digital plug, sensor material graphite, cell constant 0.475 cm-1, temp.-sensor NTC 30 kOhm, length 120 mm, 15.3 mm Ø, -5...+80 °C LF413T3MForkIDS 285206290IDS ® 4 pole cond. cell for small sample volumina, plastic shaft, 3 m cable with digital plug, sensor material graphite, cell con- stant 0.47 cm-1, temp.-sensor NTC 30 kOhm,minimum imm- mersion depth 16 mm, length 120 mm, 15.3 mm Ø, -5...+80 °C IDS ® Sensors 13 12 We are Xylem Analytics Xylem consists of three business sectors - Water Solutions, Applied Water Systems and Analytics. The following companies make up Xylem Analytics and act like SI Analytics in the chemical, pharmaceutical, biotechnological, food and plastics industries. Furthermore, Xylem Analytics comprises: Our company name - SI Analytics - already expresses our core competency - the manufacturing of analysis equipment. Furthermore, SI stands for the main products of our company: Sensors and Instruments. We have risen from the history of SCHOTT® AG and SI Analytics can offer 75 years of experience in glass technology and the development of analysis equipment. We will continue to develop and manufacture our products with the highest requirements of innovation and quality. We have been an independent enterprise for over 40 years, and as a former subsidiary of SCHOTT® AG, we continue to value tradition and manufacture in the footsteps of traditional Mainz glass manufacturers. Our electrodes, meters, titrators and capillary viscosimeters will continue to have their home in areas, where the know-how in analytic measurement technology is in demand. SI Analytics has been part of the listed company Xylem Inc. since 2011, which is headquartered in Rye Brook / N.Y., USA. Xylem is a leading worldwide provider of problem solutions regarding water. Your work is your SIgnature. SI Analytics Bellingham & Stanley For almost a century, Bellingham + Stanley has been the leader in the field of: • Refractometers • Polarimeters • Certified Reference Materials www.bellinghamandstanley.com ebro ebro has been servicing the scientific world with innovative temperature measurement solutions for over forty years and today, customer feedback still plays an important role within the business model. To ebro, customer care not only means supporting existing product and software; it also means being able to provide custom solutions within their field of excellence too! • Precision thermometers • Food Safety test kits • Frying oil monitors • Humidity, vacuum & temperature dataloggers • Portable digital refractometers www.ebro.com OI Analytical Since 1963 OI Analytical has been providing innovative products used for chemical analysis and is a key supplier of sample preparation and turn-key analytical solutions for testing food products and water for chemical contaminants. Beverage & water analyses include the determination of: • Total Organic Carbon (TOC) & cyanide • Organophosphorus & organochlorine pesticides • Volatile Organic Compounds (VOCs) Sample preparation for food and fruit analyses include: • Antibiotics & mycotoxins • Organophosphorus pesticides • Organochlorine pesticides www.oico.com 15 14 presented by What can Xylem do for you? We’re 12,700 people unified in a common purpose: creating innovative solutions to meet our world’s water needs. Developing new technologies that will improve the way water is used, conserved, and re-used in the future is central to our work. We move, treat, analyze, and return water to the environment, and we help people use water efficiently, in their homes, buildings, factories and farms. In more than 150 countries, we have strong, long-standing relationships with customers who know us for our powerful combination of leading product brands and applications expertise, backed by a legacy of innovation. For more information on how Xylem can help you, go to www.xyleminc.comFor customers in North America: SI Analytics P.O. Box 9010 151 Graham Road College Station, Texas 77842-9010 USA Toll-free: 866-691-7954 Local: 979 690 5563 E-Mail: information.request@xyleminc.com Internet: www.si-analytics.com SI Analytics is a trademark of Xylem Inc. or one of its subsidiaries. © 2015 Xylem, Inc. 980 090US Version 08/2015 SI Analytics GmbH Hattenbergstr. 10 55122 Mainz Germany Phone: +49.(0)6131.66.5111 Fax: +49.(0)6131.66.5001 E-Mail: si-analytics@xyleminc.com Internet: www.si-analytics.com